Opis

• Tytuł:
  3-Substituted Blatter Radicals: Cyclization of N-Arylguanidines and N-Arylamidines to Benzo[e][1,2,4]triazines and PhLi Addition
• Twórca:
  Pomikło, Dominika;
  Bodzioch, Agnieszka;
  Kaszynski, Piotr
• Współtwórca:
  Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, 90-363 Łodź , Poland;
  Department of Chemistry, Middle Tennessee State University, Murfreesboro, Tennessee 37132, United States;
  Faculty of Chemistry, University of Lodz , 91-403 Łódź, Poland
• Opis:
  A series of 3-amino- and 3-alkyl-substituted 1-phenyl-1,4-dihydrobenzo[e][1,2,4]triazin-4-yls was prepared in four steps involving N-arylation, cyclization of N-arylguanidines and N-arylamidines, reduction of the resulting N-oxides to benzo[e][1,2,4]triazines, and subsequent addition of PhLi followed by aerial oxidation. The resulting seven C(3)-substituted benzo[e][1,2,4]triazin-4-yls were analyzed by spectroscopic and electrochemical methods augmented with density functional theory (DFT) methods. Electrochemical data were compared to DFT results and correlated with substituent parameters.;
  This work was supported by the Foundation for Polish Science Grant (TEAM/2016-3/24) and National Science Centre (2020/38/A/ST4/00597).
• Dostępność obiektu:
  Dostęp otwarty
• Prawa:
  Uznanie autorstwa 4.0 Międzynarodowe;
  http://creativecommons.org/licenses/by/4.0
• Data:
  2024.03.27;
  2023.02.17
• Typ:
  Article
• Język:
  angielski
• Format:
  application/pdf
• Wydawca:
  American Chemical Society
• Relacja:
  The Journal of Organic Chemistry;;
  88
• Identyfikator:
  J. Org. Chem. 2023, 88, 5, 2999–3011;
  http://hdl.handle.net/11089/51161 ;
  10.1021/acs.joc.2c02703
• Dostawca danych:
  Repozytorium Uniwersytetu Łódzkiego
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