Object's details: Studies of the complexation behavior of tetramorpholinylo-PNP-lariat ether with Ag(I), Ca(II), Cd(II), Cu(II) and Pb(II) using Electrospray Ionization Mass Spectrometry

Provider:Repozytorium Uniwersytetu Łódzkiego

Description

Title:
Studies of the complexation behavior of tetramorpholinylo-PNP-lariat ether with Ag(I), Ca(II), Cd(II), Cu(II) and Pb(II) using Electrospray Ionization Mass Spectrometry
Creator:
Gutowska, Natalia;
Pasternak, Beata;
Seliger, Piotr;
Andrijewski, Grzegorz
Contributor:
Faculty of Chemistry, University of Lodz
Description:
In this publication the cationic metal complexes of tetramorpholinylo-PNP-lariat ether have been studied using electrospray ionization mass spectrometry (ESI-MS). The tandem mass spectra (MS/MS) of these complexes have also been tested to evaluate the stability of the different types of the complexes formed. As occurred, all selected metal cations form the complexes with 1 : 1 stoichiometry with the investigated ligand. Only silver ions create a ‘‘sandwich’’ type complex. Furthermore, the divalent cations form complexes with the nitrate anion adduct. In the case of Ca(II), Cd(II) and Pb(II) we also observed another type of the species with an additional water molecule attached to the parent complex.
Object availability:
free access
Rights:
Uznanie autorstwa-Użycie niekomercyjne-Bez utworów zależnych 3.0 Polska;
http://creativecommons.org/licenses/by-nc-nd/3.0/pl
Date:
2014.12.30;
2014.12.17
Type:
Article
Language:
English
Format:
application/pdf;
image/gif
Publisher:
The Royal Society of Chemistry;
K. Vekey, J. Chromatogr. A, 2001, 921, 227–236
Relation:
New Journal of Chemistry;2015, Nr 1
Identifier:
1369-9261;
http://hdl.handle.net/11089/6009
Data provider:
Repozytorium Uniwersytetu Łódzkiego

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Object's details: Studies of the complexation behavior of tetramorpholinylo-PNP-lariat ether with Ag(I), Ca(II), Cd(II), Cu(II) and Pb(II) using Electrospray Ionization Mass Spectrometry

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