Object's details: Doubly-bridged PNP-lariat ethers and their complexes with silver(I) ions in methanol solution

Provider:Repozytorium Uniwersytetu Łódzkiego

Description

Title:
Doubly-bridged PNP-lariat ethers and their complexes with silver(I) ions in methanol solution
Creator:
Sołtys, Natalia;
Seliger, Piotr;
Andrijewski, Grzegorz;
Siwy, Mariola
Description:
Publikacja w ramach programu Royal Society of Chemistry "Gold for Gold" 2013 finansowanego przez Uniwersytet Łódzki;
We report the preparation of four new double-bridged PNP-lariat etherderivatives L1 – L4 synthesized from precursor 1 by the subsequent substitution of chlorine atoms. The process consists of two steps. In the fi rst one two reactive chlorine atoms of the – PCl 2 exocyclic moiety are substituted with respective nucleophiles: 2,2 0 -thiodiethanethiol 2 and 2,2 0 -oxydiethanethiol 3 . In the second step the other chlorine atoms are substituted by aziridynyl 6 and pyrrolidinyl 7 groups, respectively. Their structures were established by MS, 1 H NMR, 31 P NMR, 13 C NMR spectroscopy. Furthermore, this work includes the investigation of complexation of silver( I ) ions with the new ligands L1 – L4 in methanol solution. The formation of the novel tetra-nuclear silver( I ) complexes were observed. Stability constants were determined using a simple potentiometric titration. 1 H NMR, 31 P NMR, 13 C NMR spectra were recorded to investigate how the complexation of silver( I ) ions by the investigated macrocyclic ligands occurs
Object availability:
free access
Rights:
Uznanie autorstwa 3.0 Polska;
http://creativecommons.org/licenses/by/3.0/pl
Date:
2013.11.18;
2013.10.21
Type:
Article
Language:
English
Format:
application/octet-stream
Publisher:
The Royal Society of Chemistry
Relation:
RSC Adv.;2013, 3
Identifier:
Soltys, Natalia and Seliger, Piotr and Andrijewski, Grzegorz and Siwy, Mariola Doubly-bridged PNP-lariat ethers and their complexes with silver(i) ions in methanol solution [in] RSCAdv., 2013, 3, 25351, DOI: 10.1039/c3ra43786h;
2046-2069;
DOI: 10.1039/c3ra43786h ;http://hdl.handle.net/11089/2817
Data provider:
Repozytorium Uniwersytetu Łódzkiego

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Object's details: Doubly-bridged PNP-lariat ethers and their complexes with silver(I) ions in methanol solution

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