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Diethyl (1-benzyl-4-phenyl-3-trifluoromethyl-1Hpyrrol-2-yl)phosphonate

Object's details: Diethyl (1-benzyl-4-phenyl-3-trifluoromethyl-1Hpyrrol-2-yl)phosphonate

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Provider:Repozytorium Uniwersytetu Łódzkiego

Description

Title:
Diethyl (1-benzyl-4-phenyl-3-trifluoromethyl-1Hpyrrol-2-yl)phosphonate
Creator:
Cal, Dariusz;
Jezuita, Anna;
Zagórski, Piotr;
Ejsmont, Krzysztof;
Zarychta, Bartosz
Contributor:
Department of Organic Chemistry, Faculty of Chemistry, University of Lodz, Tamka 12;
Faculty of Chemistry, University of Opole, Oleska 48, 45-052 Opole, Poland
Description:
In the title compound, C22H23F3NO3P, the dihedral angles between the pyrrole ring and the benzyl and phenyl rings are 81.38 (7) and 46.21 (8)°, respectively. The ethyl phosphate groups present with P—O—C—C torsion angles of −178.47 (10) and 106.72 (16)°, and an intramolecular C—H...O hydrogen bond occurs. In the extended structure, molecules are linked by C—H...O and C—H...F hydrogen bonds to generate [001] chains.
Object availability:
free access
Rights:
Uznanie autorstwa 4.0 Międzynarodowe;
http://creativecommons.org/licenses/by/4.0
Date:
2021.09.09;
2017
Type:
Article
Language:
English
Format:
application/pdf
Publisher:
W. T. A. Harrison, University of Aberdeen, Scotland
Relation:
IUCrData;
Subject:
crystal structure;
fluorinated heterocycles;
phosphonyl group
Identifier:
2414-3146;
http://hdl.handle.net/11089/39016 ;https://doi.org/10.1107/S2414314617011221
Data provider:
Repozytorium Uniwersytetu Łódzkiego

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Type:
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