Object's details: Crystal structure of (E)-1,2-diferrocenyl-1,2-bis(furan-2-yl)ethene

Provider:Repozytorium Uniwersytetu Łódzkiego

Description

Title:
Crystal structure of (E)-1,2-diferrocenyl-1,2-bis(furan-2-yl)ethene
Creator:
Mloston, Grzegorz;
Hamera-Fałdyga, Róża;
Linden, Anthony;
Heimgartner, Heinz
Contributor:
Department of Organic and Applied Chemistry, University of Łódź, Tamka 12, PL-91-403 Łódź, Poland;
Department of Chemistry, University of Zurich, Winterthurerstrasse 190, CH-8057 Zurich, Switzerland;
anthony.linden@chem.uzh.ch
Description:
The title compound, [Fe₂(C₅H₅)₂(C₂₀H₁₄O₂)], is the product of a new synthetic route towards tetraaryl/hetaryl-substituted ethenes that reduces the occurrence of side-products. In the crystal, the molecule is centrosymmetric and the cyclopentadienyl (Cp) rings are nearly coplanar and aligned slightly closer to a staggered conformation than to an eclipsed one. The ethene plane is tilted by 32.40 (18)° with respect to that of the substituted Cp ring and by 63.19 (19)° with respect to that of the furan ring. C—H··· π interactions link the molecules into a three-dimensional supramolecular framework.;
Funding for this research was provided by: Maestro-3 (grant No. Dec-2012/06/A/ST5/00219 to R. Hamera-Fałdyga, G. Mlostoń); Institutspartnerschaft, Alexander von Humboldt Foundation, Bonn (grant to R. Hamera-Fałdyga, G. Mlostoń).
Object availability:
free access
Rights:
Uznanie autorstwa 4.0 Międzynarodowe;
http://creativecommons.org/licenses/by/4.0
Date:
2022.01.31;
2018
Type:
Article
Language:
English
Format:
application/pdf
Publisher:
International Union of Crystallography
Relation:
Acta Crystallographica Section E: Crystallographic Communications;74;
5
Subject:
crystal structure;
ethenes;
ferrocene
Identifier:
2056-9890;
http://hdl.handle.net/11089/40538 ;
10.1107/S2056989018005078
Data provider:
Repozytorium Uniwersytetu Łódzkiego

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Object's details: Crystal structure of (E)-1,2-diferrocenyl-1,2-bis­(furan-2-yl)ethene

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