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THE REACTION OF TETRAMETHYLSILANE WITH BORON TRIBROMIDE

Object's details: THE REACTION OF TETRAMETHYLSILANE WITH BORON TRIBROMIDE

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Provider:Repozytorium Uniwersytetu Łódzkiego

Description

Title:
THE REACTION OF TETRAMETHYLSILANE WITH BORON TRIBROMIDE
Creator:
Lewkowski, Jarosław;
Vaultier, Michel
Contributor:
Jarosław Lewkowski - Department of Organic Chemistry, University of Lodz, Narutowicza 68, 90-136 Lodz, Poland;
Michel Vaultier - Synthese et Eiectrosynthese Organique, UMR 6510 associe au CNRS, Universite Rennes 1, F-35042 Rennes cedex, France
Description:
The reaction of tetramethylsilane with boron tribromide in deuterochloroform in ambient temperature or at 40°C led to bromotrimethylsilane (3) and to dibromomethylborane (4). Identity of products was confirmed by NMR spectroscopy. Analogical reaction carried out in 1,3-dichloropropane allowed to separate products of the reaction and to obtain them in 68% and 59% yields respectively.;
CNRS France
Object availability:
free access
Date:
2014.08.26;
2001.12.01
Type:
Article
Language:
English
Format:
application/pdf
Publisher:
Walter de Gruyter (Previously published by Freund Publishing House Ltd.)
Relation:
Main Group Metal Chemistry;Vol. 24, No. 01, 2001
Subject:
Tetramethylsilane;
boron tribromide;
bromine replacement;
dibromomethylborane
Identifier:
2191-0219;
http://hdl.handle.net/11089/5329
Data provider:
Repozytorium Uniwersytetu Łódzkiego

Can I use it?:
seek permission
Type:
image

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