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Addition of Di(trimethylsilyl) Phosphite to Schiff Bases of 2,5-Diformylfuran

Object's details: Addition of Di(trimethylsilyl) Phosphite to Schiff Bases of 2,5-Diformylfuran

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Provider:Repozytorium Uniwersytetu Łódzkiego

Description

Title:
Addition of Di(trimethylsilyl) Phosphite to Schiff Bases of 2,5-Diformylfuran
Creator:
Lewkowski, Jarosław;
Dzięgielewski, Marek;
Szcześniak, Aleksandra;
Ciechańska, Magdalena
Contributor:
Dept of Organic Chemistry, Faculty of Chemistry, University of Łódź, Tamka 12, 91-403 Łódź, POLAND
Description:
A series of 2,5-Furanyl-bis-(aminomethylphosphonic Acids) has been synthesized by the addition of di(trimethylsilyl) phosphite to azomethine bond of achiral Schiff bases derved from 2,5-diformylfuran. The stereochemical aspect of this reaction has been studied and compared with the behaviour of achiral terephthalic Schiff bases in similar reaction. Whereas, addition to achiral terephthalic Schiff bases was found to be highly stereoselective, the analogous reaction with achiral 2,5-diformylfuran Schiff bases was stereoselective exclusively in the case when the substituent is benzyl.;
N/A
Object availability:
free access
Date:
2014.08.27;
2011.11
Type:
Article
Language:
English
Format:
application/pdf
Publisher:
MedJChem
Relation:
Mediterranean Journal of Chemistry;2011, 1(3)
Subject:
2,5-diformylfuran Schiff bases;
di(trimethylsilyl) phosphite;
addition;
azomethine bond
Identifier:
2028 - 3997;
http://hdl.handle.net/11089/5342
Data provider:
Repozytorium Uniwersytetu Łódzkiego

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