Description

• Title:
  [closo-B10H8-1,10-(COOH)2]2−: a building block for functional materials?
• Creator:
  Kapuściński, Szymon;
  Hietsoi, Oleksandr;
  Pietrzak, Anna;
  Friedli, Andrienne C.;
  Kaszyński, Piotr
• Contributor:
  Department of Chemistry, Middle Tennessee State University, Murfreesboro, Tennessee 37132, United States;
  Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences, 90-363 Łodź , Poland;
  Faculty of Chemistry, Łodź University of Technology, 90-924 Łodź , Poland;
  Faculty of Chemistry, University of Łodź , 91-403 ́ Łodź , Poland
• Description:
  [closo-B10H8-1,10-(COOH)2]2− was obtained in five steps and 40% overall yield from [closo-B10H10]2−. It can be converted to [closo-B10H8-1,10-(CO)2] and subsequently to carbonium ylides [closo-B10H8-1-COOH-10-(C(NRCH2)2)]. The diacid, its derivatives, and di-ylide [closo-B10H8-1,10-(C(NHMe)2)2] are characterized by spectroscopic and single crystal XRD methods augmented with DFT results.;
  This work was supported by the National Science Foundation (DMR-1611250 and XRD facility CHE-1626549 grants) and Narodowe Centrum Nauki (2020/38/A/ST4/00597) grants.
• Object availability:
  free access
• Date:
  2024.03.27;
  2021.12.15
• Type:
  Article
• Language:
  English
• Format:
  application/pdf
• Publisher:
  Royal Society of Chemistry Journals
• Relation:
  Chemical Communications;;
  58
• Identifier:
  Chem. Commun., 2022,58, 851-854;
  http://hdl.handle.net/11089/51176 ;
  10.1039/D1CC06485A
• Data provider:
  Repozytorium Uniwersytetu Łódzkiego
• Can I use it?:
  seek permission
• Type:
  image