Description

• Title:
  [μ-2-Methyl-5-(methyl­sulfanylmeth­yl)aza­ferrocene]bis­­(penta­carbonyl­tungsten)
• Creator:
  Kowalski, Konrad;
  White, Andrew J.P.
• Contributor:
  Department of Organic Chemistry, University of Łódź, 90-136 Łódź, Narutowicza 68, Poland;
  Department of Chemistry, Imperial College London, South Kensington, London SW 7AZ, England;
  kondor15@wp.pl
• Description:
  The title compound, [W2Fe(C5H5)(C7H10NS)(CO)10], was prepared by reaction of 5-methyl­sulfanylmethyl-2-methyl aza­ferrocene with photochemically generated [W(CO)5]·THF. The X-ray structural analysis showed the azaferrocenyl unit to have adopted a nearly eclipsed geometry. The geometries at the two tungsten centers are distorted octahedral.;
  We acknowledge financial support from Imperial College London and the University of Łodz.
• Object availability:
  free access
• Rights:
  Uznanie autorstwa 4.0 Międzynarodowe;
  http://creativecommons.org/licenses/by/4.0
• Date:
  2022.02.12;
  2007
• Type:
  Article
• Language:
  English
• Format:
  application/pdf
• Publisher:
  International Union of Crystallography
• Relation:
  Acta Crystallographica Section E: Crystallographic Communications;63;
  2
• Subject:
  Single-crystal X-ray study;
  T = 173 K;
  Mean σ(C–C) = 0.005 Å;
  R factor = 0.025;
  wR factor = 0.063;
  Data-to-parameter ratio = 25.5
• Identifier:
  2056-9890;
  http://hdl.handle.net/11089/40631 ;
  1600-5368;
  10.1107/S1600536806056121
• Data provider:
  Repozytorium Uniwersytetu Łódzkiego
• Can I use it?:
  check license
• Type:
  image